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  • ASTM
    D4423-10 Standard Test Method for Determination of Carbonyls In C4 Hydrocarbons
    Edition: 2010
    $82.37
    Unlimited Users per year

Description of ASTM-D4423 2010

ASTM D4423 - 10

Standard Test Method for Determination of Carbonyls In C 4 Hydrocarbons

Active Standard ASTM D4423 | Developed by Subcommittee: D02.D0.04

Book of Standards Volume: 05.02



Translated Standard: Russian
more info


ASTM D4423

Significance and Use

The determination of the carbonyl content of polymerization-grade 1,3-butadiene is necessary, since in some polymerization reactions, the presence of carbonyls in excess over some specified amount can have a deleterious effect upon the polymer properties or the reaction itself, or both.

1. Scope

1.1 This test method covers the determination of carbonyls (ketones and aldehydes) in C 4 hydrocarbons. This test method was tested on polymerization-grade 1,3-butadiene.

1.2 The applicable range for this test method is 0 to 50 mg/kg carbonyls calculated as acetaldehyde.

1.3 Other C 4 hydrocarbons and their mixtures besides polymerization-grade 1,3-butadiene could be tested using this same test method. However, the precision section of this test method covers only carbonyls in applicable range as listed in 1.2, as found in polymerization-grade 1,3-butadiene.

1.4 WARNING Mercury has been designated by many regulatory agencies as a hazardous material that can cause central nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Material Safety Data Sheet (MSDS) for details and EPA s website http://www.epa.gov/mercury/faq.htm for additional information. Users should be aware that selling mercury and/or mercury containing products into your state or country may be prohibited by law.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

D484 Specification for Hydrocarbon Dry Cleaning Solvents

D1193 Specification for Reagent Water

E1 Specification for ASTM Liquid-in-Glass Thermometers


Keywords

butadiene; C 4 hydrocarbons; carbonyls; titration; Aldehydes; Carbonyl content; Hydrocarbons--C 1 -C 5 (and lighter); Ketones; Titration ;


ICS Code

ICS Number Code 71.080.80 (Aldehydes and ketones)


DOI: 10.1520/D4423-10

ASTM International is a member of CrossRef.

ASTM D4423

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ASTM International, formerly known as the American Society for Testing and Materials (ASTM), is a globally recognized leader in the development and delivery of international voluntary consensus standards. Today, some 12,000 ASTM standards are used around the world to improve product quality, enhance safety, facilitate market access and trade, and build consumer confidence. ASTM’s leadership in international standards development is driven by the contributions of its members: more than 30,000 of the world’s top technical experts and business professionals representing 150 countries. Working in an open and transparent process and using ASTM’s advanced electronic infrastructure, ASTM members deliver the test methods, specifications, guides, and practices that support industries and governments worldwide.

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